Time-resolved dissolution elucidates the mechanism of zeolite MFI crystallization
نویسندگان
چکیده
Unbiased zeolite dissolution removes defects in the structure, enabling retroactive assessment of crystallization history.
منابع مشابه
Tubular MFI Zeolite Membranes Made by In-Situ Crystallization
Polycrystalline MFI zeolite membranes were prepared on α-alumina tubular support by hydrothermal treatments at 413 K. The synthesized zeolite membranes were characterized by XRD, SEM and single gas permeation. The influence of hydrothermal treatment steps and the calcination time on the zeolite layer formation were investigated. MFI zeolite membrane prepared by four subsequent hydrothermal ...
متن کاملtubular mfi zeolite membranes made by in-situ crystallization
polycrystalline mfi zeolite membranes were prepared on α-alumina tubular support by hydrothermal treatments at 413 k. the synthesized zeolite membranes were characterized by xrd, sem and single gas permeation. the influence of hydrothermal treatment steps and the calcination time on the zeolite layer formation were investigated. mfi zeolite membrane prepared by four subsequent hydrothermal trea...
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The first direct transmission electron microscopic (TEM) observation has been carried out on the continuous monocrystal-thick b-oriented pure silica zeolite MFI films produced by in situ crystallization. The self-supporting film samples for TEM study were fabricated by dissolving the steel substrate with acid. This TEM study is free of those artifacts that are typically associated with TEM samp...
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A new route to the synthesis of highly b-oriented zeolite MFI films is demonstrated for the first time using ammonium salts as crystallization-mediating agents in secondary growth. The ammonium salts tailor the crystallization process and silicate-NH4(+) interactions dominate over TPA-NH4(+) interactions so that nucleation was effectively suppressed during secondary growth.
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ژورنال
عنوان ژورنال: Science Advances
سال: 2021
ISSN: ['2375-2548']
DOI: https://doi.org/10.1126/sciadv.abg0454